Scorpio

During the Defenders' run-in with the Zodiac, the villain Scorpio led the astrological organization. The true identify of Scorpio was Jake Fury, the complicated brother of S.H.I.E.L.D. agent Nick Fury.

Spidey Super Stories #34 presented a friendlier version of the Zodiac. In this story, three extraterrestrials with animal-like features returned to Earth after visiting the planet thousands of years ago. Upon their return, the extraterrestrials named Leo, Aries, and Taurus encountered the super-villain Scorpion, a long-time nemesis of Spider-Man. Although the extraterrestrials initially trusted Scorpion because he resembled their crew mate Scorpio, they soon grew wise to Scorpion's plans to dupe them into committing crimes.

Spidey Super Stories. Vol. 1. No. 34. May 1978. "Spidey Meets the Zodiac People." J.M. Salicrup/Nick Cuti (writers), Win Mortimer, Ron Perlin & Mike Esposito (artists), A.J. Hays/Julie Mishkin (editors), David Kraft (Marvel consultant), Marie Severin (art director).